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Record W2915208893 · doi:10.1002/prs.12045

Experimental and theoretical investigation of the lower explosion limit of multiphase hybrid mixtures

2019· article· en· W2915208893 on OpenAlexaff
Emmanuel Kwasi Addai, Haider Jebur Ali, Paul Amyotte, Ulrich Krause

Bibliographic record

VenueProcess Safety Progress · 2019
Typearticle
Languageen
FieldEngineering
TopicCombustion and Detonation Processes
Canadian institutionsDalhousie University
Fundersnot available
KeywordsMethaneCoal dustDust explosionSolventChemistryHydrogenNuclear engineeringCoalWaste managementChemical engineeringEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

This article reports on experimental and theoretical investigations of the lower explosion limits of two‐ and three‐phase mixtures such as gas‐dust, spray‐gas, dust‐spray, and dust‐gas‐spray. The materials used were lycopodium and brown coal as combustible dusts, methane, and hydrogen as combustible gases and ethanol and isopropanol as sprays (liquid solvent). The experiments were performed in the standardized 20‐L spherical explosion chamber where modifications were done to allow the input of solvents and gases. The test protocol was in accordance with the European standard, EN 14034. The experimental results demonstrate significant enhancements in explosion likelihood brought about by gas or spray admixture with dust and vice versa. They also confirm that a hybrid mixture explosion is possible even when both dust and spray or gas concentrations are respectively lower than their minimum explosible concentration (MEC) and lower explosion limit (LEL). For example, the MEC of brown coal decreases from 250 to 60 g/m 3 , 60 and 100 g/m 3 when small amounts of isopropanol spray, methane gas, and hydrogen gas respectively, were added (even though these concentrations of gases and solvents are all below the LEL of the individual substances). Comparisons have been made between the lower explosible limit of the experimental data and classical models such as those developed by Bartknecht, Le Chatelier, and Jiang and coworkers. This research provides safety practitioners with a practical means to characterize material hazards without the need to perform a large number of tests. © 2019 American Institute of Chemical Engineers Process Saf Prog, 1–13: e12045 2019

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.232
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2019
Admission routes1
Has abstractyes

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