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Record W2915208893 · doi:10.1002/prs.12045

Experimental and theoretical investigation of the lower explosion limit of multiphase hybrid mixtures

2019· article· en· W2915208893 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueProcess Safety Progress · 2019
Typearticle
Languageen
FieldEngineering
TopicCombustion and Detonation Processes
Canadian institutionsDalhousie University
Fundersnot available
KeywordsMethaneCoal dustDust explosionSolventChemistryHydrogenNuclear engineeringCoalWaste managementChemical engineeringEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

This article reports on experimental and theoretical investigations of the lower explosion limits of two‐ and three‐phase mixtures such as gas‐dust, spray‐gas, dust‐spray, and dust‐gas‐spray. The materials used were lycopodium and brown coal as combustible dusts, methane, and hydrogen as combustible gases and ethanol and isopropanol as sprays (liquid solvent). The experiments were performed in the standardized 20‐L spherical explosion chamber where modifications were done to allow the input of solvents and gases. The test protocol was in accordance with the European standard, EN 14034. The experimental results demonstrate significant enhancements in explosion likelihood brought about by gas or spray admixture with dust and vice versa. They also confirm that a hybrid mixture explosion is possible even when both dust and spray or gas concentrations are respectively lower than their minimum explosible concentration (MEC) and lower explosion limit (LEL). For example, the MEC of brown coal decreases from 250 to 60 g/m 3 , 60 and 100 g/m 3 when small amounts of isopropanol spray, methane gas, and hydrogen gas respectively, were added (even though these concentrations of gases and solvents are all below the LEL of the individual substances). Comparisons have been made between the lower explosible limit of the experimental data and classical models such as those developed by Bartknecht, Le Chatelier, and Jiang and coworkers. This research provides safety practitioners with a practical means to characterize material hazards without the need to perform a large number of tests. © 2019 American Institute of Chemical Engineers Process Saf Prog, 1–13: e12045 2019

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.377
Threshold uncertainty score0.309

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.232
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it