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Record W2933147152 · doi:10.1021/acssuschemeng.9b00689

Sustainable Hydrophobic and Moisture-Resistant Coating Derived from Downstream Corn Oil

2019· article· en· W2933147152 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2019
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsUniversity of Guelph
FundersAgriculture and Agri-Food CanadaNatural Sciences and Engineering Research Council of CanadaOntario Ministry of Agriculture, Food and Rural AffairsUniversity of Guelph
KeywordsCoatingSuperhydrophobic coatingContact angleMoistureChemical engineeringMaterials scienceSilanePolymerSubstrate (aquarium)CelluloseComposite materialOrganic chemistryChemistry

Abstract

fetched live from OpenAlex

Sustainable coating as a replacement for petroleum-derived materials is highly required for packaging and other applications to reduce the generation of land and ocean pollution. In this study, a novel approach has been introduced to incorporate hydrolyzable silane (−Si–OCH2CH3) groups in the downstream corn oil backbone (one of the coproducts of bioethanol industry) which has been consequently used for the fabrication of hydrophobic and moisture-resistant coating for paper substrate. Scanning electron microscopy (SEM) images confirmed the uniform coating of the silane-modified epoxidized downstream corn oil (SECO) over the paper. The condensation reaction has taken place with the hydroxyl group of paper and SECO, and as a result, the number of surface hydroxyl group was reduced to make a hydrophobic surface on coated paper with static water contact angle (WCA) of 129.4 ± 1.12°. SECO-coated paper showed almost 67% decrease in specific water vapor transmission rate compared to that of the uncoated filter paper. These results indicate that the SECO coating delivers excellent moisture barrier and hydrophobicity to the paper substrate. Thus, SECO might be a competitive substitute to petroleum-based polymers for fluorine-free hydrophobic and moisture-resistant coating. This research finding can find application especially in huge paper packaging industries as well as cellulose-based products such as fiber and foam.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.183
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it