MétaCan
Menu
Back to cohort
Record W2943636048 · doi:10.1021/acsomega.9b01110

Study of the Partial Charge Transport Properties in the Molten Alumina via Molecular Dynamics

2019· article· en· W2943636048 on OpenAlexafffund
Aïmen E. Gheribi, Alessandra Serva, Mathieu Salanne, Kelly Machado, Didier Zanghi, Catherine Bessada, Patrice Chartrand

Bibliographic record

VenueACS Omega · 2019
Typearticle
Languageen
FieldChemical Engineering
TopicMolten salt chemistry and electrochemical processes
Canadian institutionsPolytechnique Montréal
FundersRio TintoNorsk HydroCanadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of CanadaAlcoa
KeywordsMolecular dynamicsContext (archaeology)Materials scienceCharge (physics)Molten saltRange (aeronautics)PolarizabilityIonic bondingChemical physicsChemistryIonMetallurgyPhysicsComputational chemistryComposite material

Abstract

fetched live from OpenAlex

Knowing the charge-transport properties of molten oxides is essential for industrial applications, particularly when attempting to control the energy required to separate a metal from its ore concentrate. Nowadays, in the context of a drastic increase of computational resources, research in industrial process simulation and their optimization is gaining popularity. Such simulations require accurate data as input for properties in a wide range of compositions, temperatures, and mechanical stresses. Unfortunately, due to their high melting points, we observe a severe lack of (reproducible) experimental data for many of the molten oxides. An alternative consists in using molecular dynamic simulations employing nonempirical force fields to predict the charge-transport properties of molten oxides and thus alleviate the lack of experimental data. Here, we study molten alumina using two polarizable force fields, with different levels of sophistication, parameterized on electronic structure calculations only. After validating the models against the experimental sets of density and electrical conductivity, we are able to determine the various ionic contributions to the overall charge transport in a wide range of temperatures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.353

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.206
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2019
Admission routes2
Has abstractyes

Explore more

Same venueACS OmegaSame topicMolten salt chemistry and electrochemical processesFrench-language works237,207