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Record W2943731834 · doi:10.1002/admi.201900186

Fabrication of a Dendrite‐Free all Solid‐State Li Metal Battery via Polymer Composite/Garnet/Polymer Composite Layered Electrolyte

2019· article· en· W2943731834 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAdvanced Materials Interfaces · 2019
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsUniversity of Calgary
FundersFord Motor Company
KeywordsMaterials scienceElectrolyteComposite numberCeramicPolymerIonic conductivityMembraneChemical engineeringFast ion conductorOxideBattery (electricity)ElectrodeComposite materialMetallurgy

Abstract

fetched live from OpenAlex

Abstract While all‐solid‐state Li metal batteries based on ceramic solid‐electrolytes offer higher energy density and better safety features over their liquid counterparts, critical challenges in their design such as high electrode–electrolyte interface resistance and formation of Li‐dendrites still remain unsolved. To address the issues, an intimate contact between Li and the solid‐state electrolyte is necessary. Herein, a flexible and mechanically robust polymer membrane comprising of poly(ethylene oxide), lithium perchlorate, and garnet particles is used as an interlayer between Li metal and garnet ceramic electrolyte. The Li salt enhances the ionic conductivity of the membranes and ensures their flexible nature while garnet particles enhance their mechanical strength. The cells comprising of composite membranes results in four times smaller charge transfer resistance at the interface and demonstrate stable and reversible Li plating/stripping voltage profiles. Further, the polymer composite membrane mechanically blocks the formation of Li dendrites at reasonably high currents (0.1 mA cm −2 ) in the structures even after prolonged cycling (140 h) owing to their enhanced toughness. With smaller charge transfer resistance (≈400 Ω cm 2 at room temperature), stability at extended periods of cycling and no Li‐dendrite formations, the structures can prove a viable electrolyte candidate for advanced solid‐state Li metal batteries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.226
Teacher spread0.219 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it