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Record W2943976458 · doi:10.1111/ggr.12269

High‐Precision Measurement of <sup>187</sup>Os/<sup>188</sup>Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐<scp>TIMS</scp> using Faraday Cups Equipped with 10<sup>13</sup> Ω Amplifiers

2019· article· en· W2943976458 on OpenAlexaff
Guiqin Wang, Hauke Vollstaedt, Jifeng Xu, Wengui Liu

Bibliographic record

VenueGeostandards and Geoanalytical Research · 2019
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGroundwater and Isotope Geochemistry
Canadian institutionsThermo Fisher Scientific (Canada)
FundersChinese Academy of SciencesNational Natural Science Foundation of China
KeywordsRepeatabilityAnalytical Chemistry (journal)Mass fractionChemistryIsotopeFraction (chemistry)HomogeneousRadiochemistryChromatographyPhysicsNuclear physics

Abstract

fetched live from OpenAlex

N ( 187 Os)/ N ( 188 Os) ratios of six geological reference materials were measured using static Faraday cups ( FC s) with 10 13 Ω amplifiers by N‐ TIMS . Our results show that the repeatability precision was 2–3‰ (2 RSD , n = 3), when taking ~ 1 g of BHVO ‐2 with 76 pg g −1 of Os mass fraction and ~ 2 g of BCR ‐2 with 21 pg g −1 of Os mass fraction for each sample, whether measured by FC s or by secondary electron multiplier. The repeatability precision measured by FC s was 1–0.2‰ (2 RSD , n = 3) when taking ~ 1 g of BIR ‐2 with 350 pg g −1 of Os mass fraction, ~ 1 g of WGB ‐1 with 493 pg g −1 of Os mass fraction or ~ 0.5 g of WPR ‐1 with 13.3 ng g −1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV ‐2 with 4 pg g −1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ ( RSD , n = 3), which is better than those measured by FC s. Of the six reference materials analysed, WPR ‐1 and BIR ‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.006
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.572
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0060.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.002
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.044
GPT teacher head0.296
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2019
Admission routes1
Has abstractyes

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