Emission spectra of atomic and molecular nitrogen from photolysis of ammonia in solid neon
Bibliographic record
Abstract
Dilute samples of NH3 and ND3 in solid neon near 4 K were irradiated at 200 or 173 or 143 nm with light from a synchrotron. We recorded emission spectra of atomic N, involving states 4So, 2Po and 2Do, and of molecular N2, involving states X 1Σg+, A 3Σu+, B 3Πg and C 3Πu in systems with vibrational progressions in the lower states. The emission spectra covered the near-ultraviolet, visible and near-infrared regions from 200 to 1100 nm; the far-ultraviolet absorption spectrum for the precursor NH3 in solid neon was also measured. Recorded for samples in darkness after irradiation at 143 nm during warming from ∼5 K to ∼8 K, thermoluminescent spectra consisted mostly of lines emitted by molecular N2. The analysis of these spectra, and their temporal development, provides information about the nature of dissociative and trapping processes in solid neon under cryogenic conditions involving monochromatic synchrotron radiation.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".