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Multiple propane gas flow rates procedure to determine accuracy and linearity of indirect calorimetry systems : An experimental assessment of a method.

2019· preprint· en· W2945190891 on OpenAlexaff
Alsubheen A Sana'a, Angela Loucks-Atlinson, Matthew Atkinson, Liam Kelly, Tim Alkanani, Fabien A. Basset

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldChemistry
Topicthermodynamics and calorimetric analyses
Canadian institutionsWestern UniversityMemorial University of Newfoundland
Fundersnot available
KeywordsPropaneChemistryCarbon dioxideCalorimetryVolumetric flow rateAnalytical Chemistry (journal)LinearityOxygenStoichiometryEnergy (signal processing)ThermodynamicsStatisticsMathematicsPhysical chemistryEnvironmental chemistryPhysicsOrganic chemistry

Abstract

fetched live from OpenAlex

Objective: Indirect calorimetry (IC) systems measure the fractions of expired carbon dioxide (F E CO 2 ) and oxygen (F E O 2 ) recorded at the mouth in order to estimate whole body energy production (EP). The fundamental principal of IC relates to oxidative mechanisms, expressed as rate of oxygen uptake (V̇O 2 ) and carbon dioxide production (V̇CO 2 ). From these volumes we calculate energy production and respiratory exchange ratio which is used to estimate substrate utilization rates. The accuracy of IC systems is critical to detect small changes in respiratory gas exchanges. The aim of this technical report was to assess the accuracy and linearity of IC systems using multiple propane gas flow rates procedure. Approach: A series of propane gas with different flow rates and ventilation rates were run on three different IC systems. The actual experimental V̇O 2 and V̇CO 2 were calculated and compared to stoichiometry theoretical values. Results: showed a linear relationship between gas volumes (V̇O 2 and V̇CO 2 ) and propane gas flows (99.6%, 99.2%, 94.8% for the Sable, Moxus, and Jaeger metabolic carts, respectively). In terms of system error, Jaeger system had significantly ( p < 0.001) greater V̇O 2 ( M = -0.057, SE = 0.004), and V̇CO 2 ( M = -0.048, SE = 0.002) error compared to either the Sable (V̇O 2 , M = 0.044, SE = 0.004; V̇CO 2 , M = 0.024, SE = 0.002) or the Moxus (V̇O2, M = 0.046, SE = 0.004; V̇CO 2 , M = 0.025, SE = 0.002) metabolic carts. There were no significant differences between the Sable or Moxus metabolic carts. Conclusion: The multiple flow rates approach permitted the assessment of linearity of IC systems in addition to determining the accuracy of fractions of expired gases.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.011
metaresearch head score (Gemma)0.023
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.011
Threshold uncertainty score0.056

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0110.023
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.363
Teacher spread0.321 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations3
Published2019
Admission routes1
Has abstractyes

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