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Record W2945997580 · doi:10.1515/zpch-2019-1384

Gamma Radiation and Hydrogen Peroxide Based Advanced Oxidation Process for the Degradation of Disperse Dye in Aqueous Medium

2019· article· en· W2945997580 on OpenAlexaff
Aneela Jamil, Tanveer Hussain Bokhari, Munawar Iqbal, Ijaz Ahmad Bhatti, Muhammad Zuber, Jan Nisar, Nasir Masood

Bibliographic record

VenueZeitschrift für Physikalische Chemie · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsMemorial University of Newfoundland
FundersHigher Education Commission, Pakistan
KeywordsAqueous solutionHydrogen peroxideChemical oxygen demandDegradation (telecommunications)Nuclear chemistryChemistryFourier transform infrared spectroscopyAdvanced oxidation processIrradiationBiochemical oxygen demandRadiolysisWastewaterHuman decontaminationChemical engineeringWaste managementCatalysisOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract In view of promising efficiency of advanced oxidation process (AOP), gamma radiation in combination with H 2 O 2 was employed for the degradation of disperse red 73 (DR73) dye. Cs-137 gamma radiation source was used for dye aqueous solution irradiation. The process variables such as pH (3–9), H 2 O 2 concentration (0.3–0.9 mL), gamma radiation absorbed dose (1–20 kGy) and DR73 initial concentration (50–150 mg/L) were optimized for maximum degradation of dye. The efficiency of AOP was evaluated on the basis of dye degradation, water quality parameters and toxicity reduction. Degradation of DR73 was achieved 69% using gamma radiation absorbed dose of 20 kGy and at the same dose 96.3% degradation was achieved in the presence of 0.9 mL/L H 2 O 2 . The dye degradation found to be dependent on dye initial concentration and pH of the medium. The radiolytic progress of DR73 was monitored by Fourier transform infrared (FTIR) and UV-Visible spectroscopy. The chemical oxygen demand (COD) and biological oxygen demand (BOD) were reduced significantly in response of treatment of dye at optimum conditions of process variables. The toxicity of treated and un-treated dye solution was monitored by haemolytic and Ames assays. Results revealed that the toxicity of DR73 dye was also reduced significantly after treatment. Findings revealed that the gamma radiation based AOPs are promising and could possibly be used for the remediation of textile wastewater contains toxic dyes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.616

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.258
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations43
Published2019
Admission routes1
Has abstractyes

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