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Record W2947153714 · doi:10.1021/acs.analchem.9b01417

Analyzing the Biochemical Alteration of Green Algae During Chronic Exposure to Triclosan Based on Synchrotron-Based Fourier Transform Infrared Spectromicroscopy

2019· article· en· W2947153714 on OpenAlexafffund
Xiaying Xin, Chunjiang An, Harold G. Weger, Guanhui Cheng, Jian Shen, Scott M. Rosendahl

Bibliographic record

VenueAnalytical Chemistry · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicPharmaceutical and Antibiotic Environmental Impacts
Canadian institutionsCanadian Light Source (Canada)Concordia UniversityUniversity of Regina
FundersCanadian Institutes of Health ResearchNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsCanada Foundation for Innovation
KeywordsTriclosanChemistryToxicityEnvironmental chemistryChronic toxicityPhosphorusFourier transform infrared spectroscopyAcute toxicityChemical engineering

Abstract

fetched live from OpenAlex

The study explored the chronic toxicity of triclosan to green microalga Chlorococcum sp. under multiple interactions among multiple environmental conditions. This is the first study on chronic algal toxicity to combine synchrotron-based Fourier transform infrared spectromicroscopy, factorial analysis, principal component analysis, and stepwise-cluster analysis. Such a combination helps to reveal the toxic mechanism at the molecular level and explore the inner correlationship among multiple environmental conditions. In the 120-h test, nitrogen content became the most significant factor of the physiochemical properties. Some insignificant factors in the 48-h test became significant in the 120-h test. Temperature * nitrogen content, temperature * phosphorus content, and pH * phosphorus content were the most significant two-order interactions. Temperature * pH * NaCl concentration and temperature * NaCl concentration * phosphorus content were the most significant three-order interactions. More high-order interactions became significant in the 120-h test, indicating the complexity and impacts of all the factors may increase when time was extended. The chronic toxicity of triclosan presented more distinguishable variations among treatments based on biochemical alterations. These results demonstrate that the sensitivity and fragility of algae to triclosan can be amplified with time extension. Long-term exposure can be applied to better evaluate and predict the environmental toxicity behavior of triclosan. It can also help with environmental evaluation and risk management of real-world triclosan toxicity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.245
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2019
Admission routes2
Has abstractyes

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