Additive induced crystallization of a twisted perylene diimide dimer within a polymer matrix
Bibliographic record
Abstract
The controlled aggregation of organic π-conjugated molecular semiconductors within a host material (often a polymer) is important for obtaining appropriate organic film morphologies and mechanical properties for optoelectronic applications. In this study, we demonstrate how we have challenged the twisting effect in perylene diimide dimers, which is known to hinder their aggregation. Indeed, a twisted N-annulated perylene diimide dimer (tPDI2N-EH) can be induced to form crystalline aggregates within a host poly-3-hexylthiophene (P3HT) polymer matrix using solution processing. The size of the aggregates can be controlled using varying amounts of the common processing solvent additive 1,8-diiodooctane (DIO) during film formation, by changing the concentration of the molecule within the polymer film, and by adjusting the film drying time. A combination of UV-visible spectroscopy, fluorescence microscopy, cross-polarized light microscopy, and atomic force microscopy were used to characterize the organic films.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".