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Record W2948951289 · doi:10.1201/9781315157818-15

MIC under Conditions of Oxygen or Nitrate Ingress

2017· book-chapter· en· W2948951289 on OpenAlexaboutno aff
Jaspreet Mand, Yin Shen, Heike Hoffmann, Gerrit Voordouw

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsnot available
Fundersnot available
KeywordsNitrateEnvironmental scienceOxygenEnvironmental chemistryChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

The majority of microbiologically influenced corrosion (MIC) scenarios occur under anoxic conditions and often implicate sulfate-reducing bacteria (SRB). These bacteria catalyze sulfate respiration and form sulfide as a metabolic end product. While SRB may be one of the most aggressive players in biocorrosion and are by far the most often studied, MIC can involve other organisms as well. The ingress of electron acceptors other than sulfate, such as oxygen or nitrate, into an SRB-dominated environment can lead to changes in the microbial community and in the corrosion threat. For instance, the partial respiration of nitrate by nitrate-reducing bacteria forms nitrite, a corrosive metabolite. The chemical reaction of oxygen or nitrite (a by-product of incomplete nitrate respiration) with SRB-produced sulfide forms polysulfides or elemental sulfur. Sulfur and polysulfides are highly corrosive, and evidence of sulfur-mediated corrosion can be seen when examining the metal surface in the form of severe 310pitting. Furthermore, changes in microbial community composition may also serve as evidence of sulfur- and polysulfide-mediated corrosion. DNA pyrotag sequencing was used to determine the microbial community compositions of field samples from a North Sea oil production site and from an Alberta oilfield. In both cases, microbial communities associated with sulfur metabolism were uncovered. An abundance of microorganisms able to oxidize aqueous sulfide using oxygen as an electron acceptor (genera Arcobacter, Sulfurospirillum, Sulfurimonas) were discovered. The potential for sulfur formation by these organisms greatly enhances corrosion threat. The fact that other bacteria capable of using elemental sulfur as an electron acceptor (genera Desulfuromonas, Desulfuromusa) were also found in these samples serves as evidence that sulfur is often produced at these sites. The presence of these different sulfur cycle microorganisms and the subsequent activity shown under oxygen or nitrate ingress is evidence for their participation in MIC.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.682
Threshold uncertainty score0.995

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.267
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2017
Admission routes1
Has abstractyes

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