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Record W2950730395 · doi:10.1021/cm061281y

Anisotropic Transport and Magnetic Properties of Ternary Uranium Antimonides U<sub>3</sub>ScSb<sub>5</sub> and U<sub>3</sub>TiSb<sub>5</sub>

2006· article· en· W2950730395 on OpenAlexaff
Arthur Mar, O. Tougait, M. Potel, Henri Noël, Elsa B. Lopes

Bibliographic record

VenueChemistry of Materials · 2006
Typearticle
Languageen
FieldPhysics and Astronomy
TopicRare-earth and actinide compounds
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsSeebeck coefficientCondensed matter physicsMagnetizationElectrical resistivity and conductivityFerromagnetismMaterials scienceAnisotropyMagnetic anisotropySingle crystalCrystal structureThermoelectric effectChemistryCrystallographyPhysicsMagnetic field

Abstract

fetched live from OpenAlex

Single needle-shaped crystals of U 3 ScSb 5 and U 3 TiSb 5 were grown in a tin flux. The structure of the new compound U 3 ScSb 5 was determined from single-crystal X-ray diffraction data (Pearson symbol hP 18, hexagonal, space group P 6 3 / mcm, Z = 2, a = 9.2145(2) Å, c = 6.1938(2) Å). The angular dependence of the magnetization has been studied. Ferromagnetic ordering develops within the ab plane at T C = 130 K for U 3 ScSb 5 and 160 K for U 3 TiSb 5, but there are essentially no magnetic interactions parallel to the c axis, confirming the high anisotropy expected from the crystal structure. In both cases, the easy axis for magnetization is the [120] direction. A sharp decrease below the ordering temperature is observed in the electrical resistivity parallel to the c axis; in contrast, the temperature dependence is much weaker within the ab plane. For U 3 TiSb 5, a second transition occurs at 25 K, possibly arising from a spin reorientation process. The thermoelectric power measured along the c axis for both compounds is positive and small at high temperatures, following approximately a linear dependence with temperature indicative of metallic behavior in this region. The thermopower exhibits a kink at the ferromagnetic transition temperature in the case of U 3 TiSb 5, but it is not so clear in the case of U 3 ScSb 5 . A change in sign of the thermopower occurs below T C for both compounds, characteristic of multiband conducting systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.024
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.178
Teacher spread0.172 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2006
Admission routes1
Has abstractyes

Explore more

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