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Record W2951443000 · doi:10.1002/chin.200433117

Regiospecific Synthesis of Alkylphenanthrenes Using a Combined Directed ortho and Remote Metalation‐Suzuki—Miyaura Cross Coupling Strategy.

2004· article· en· W2951443000 on OpenAlexaff
Xiongwei Cai, R. Stephen Brown, Peter V. Hodson, Victor Snieckus

Bibliographic record

VenueChemInform · 2004
Typearticle
Languageen
FieldChemistry
TopicCatalytic Cross-Coupling Reactions
Canadian institutionsQueen's University
Fundersnot available
KeywordsChemistryMetalationCombinatorial chemistryCoupling (piping)Coupling reactionOrganic chemistryStereochemistryCatalysis

Abstract

fetched live from OpenAlex

ChemInformVolume 35, Issue 33 Isocyclic Compounds Regiospecific Synthesis of Alkylphenanthrenes Using a Combined Directed ortho and Remote Metalation-Suzuki—Miyaura Cross Coupling Strategy. Xiongwei Cai, Xiongwei Cai Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorStephen Brown, Stephen Brown Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorPeter Hodson, Peter Hodson Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorVictor Snieckus, Victor Snieckus Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this author Xiongwei Cai, Xiongwei Cai Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorStephen Brown, Stephen Brown Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorPeter Hodson, Peter Hodson Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this authorVictor Snieckus, Victor Snieckus Dep. Chem., Queen′s Univ., Kingston, Ont. K7L 3N6, Can.Search for more papers by this author First published: 23 July 2004 https://doi.org/10.1002/chin.200433117Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article. Volume35, Issue33August 17, 2004 RelatedInformation

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.019
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.286
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2004
Admission routes1
Has abstractyes

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