Synthesis and Crystal Structure of Pd<sub>5</sub>InSe
Bibliographic record
Abstract
Pd5InSe has been prepared from the elements. The use of iodine as a mineralizing agent enables the synthesis of single-phase powder samples as well as of single crystals. Pd5InSe is stable in cold air, but reacts to give Pd, In2O3 and Pd4Se at 400 °C. The crystal structure of Pd5InSe was determined from single-crystal X-ray diffraction data (space group P4=mmm, a = 4.0255(7), c = 6.972(1) Å, z(Pd2) = 0.28111(8)) and belongs to the Pd5TlAs-type structure with full occupation of all atomic sites. EDX analysis on the single crystal (Pd5.0(1)In0.99(3)Se1.0(1)) confirms the stoichiometric composition. The relationship to the cubic close packing (Cu-type structure), which may be visualized by the crystal chemical formula Pd4PdTlAs⃞, is proven by a Bärnighausen symmetry tree.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".