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Record W2955574694 · doi:10.1039/c9ra02332a

Nitrogen/phosphorus synergistic flame retardant-filled flexible polyurethane foams: microstructure, compressive stress, sound absorption, and combustion resistance

2019· article· en· W2955574694 on OpenAlexaff
Ting‐Ting Li, Mengfan Xing, Hongyang Wang, Shih‐Yu Huang, Chengeng Fu, Ching‐Wen Lou, Jia-Horng Lin

Bibliographic record

VenueRSC Advances · 2019
Typearticle
Languageen
FieldMaterials Science
TopicFlame retardant materials and properties
Canadian institutionsNovelis (Canada)
FundersGreen Dyeing and Finishing Engineering Research Center of Fujian UniversityNatural Science Foundation of Tianjin CityTianjin UniversityMinjiang UniversityNatural Science Foundation of Fujian ProvinceNational Natural Science Foundation of China
KeywordsFire retardantPolyurethaneMaterials scienceCompressive strengthMicrostructureComposite materialCombustionAbsorption (acoustics)NitrogenPhosphorusChemical engineeringChemistryMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

Compared with a rigid polyurethane foam, a flexible polyurethane foam (FPUF) has more diversified applications including filtration, sound absorption, vibration-proofing, decoration, packaging, and heat insulation. However, its most potential hazard is flammability. Therefore, in this study, we focused on improving its flame retardation and then tested its sound absorption with the addition of nitrogen/phosphorus synergistic flame retardants. The influence of phosphorus-based flame retardants (TCPP, TDCP, and V6) and a nitrogen/phosphorus synergistic flame retardant (melamine-TDCP) on its microstructure, compressive stress, sound absorption, thermal stability, and flame retardation was systematically explored. The presence of phosphorus flame retardants improved the sound absorption but considerably decreased the mechanical properties. The melamine-TDCP compound flame retardant delivered smaller cells and thus increased the compression property of the resulting foam. Moreover, with a higher content of melamine, the initial mass-loss temperature also increased. In particular, on using TDCP and 5 wt% of melamine as flame retardants, the compressive stress increased by 3.4 times, the average sound absorption coefficient was 0.45, and LOI reached 25.5, which met the requirements of industrial flame retardant/sound absorbent materials. This resultant flame retardant/sound absorbent flexible polyurethane foam can serve as a mattress and furniture pad material, vehicle seat cushion material, and liner for laminated composites in the future.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.001

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.225
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations39
Published2019
Admission routes1
Has abstractyes

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