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Record W2969653430 · doi:10.1029/2019jd031111

Modeled and Observed Volcanic Aerosol Control on Stratospheric NO<sub>y</sub> and Cl<sub>y</sub>

2019· article· en· W2969653430 on OpenAlexaff
Brian Zambri, Susan Solomon, Douglas E. Kinnison, Michael Mills, Anja Schmidt, Ryan R. Neely, Adam Bourassa, Douglas A. Degenstein, Chris Roth

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2019
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of Saskatchewan
FundersNational Science Foundation of Sri LankaNatural Environment Research CouncilSight Research UKNational Center for Atmospheric ResearchNational Science Foundation
KeywordsAerosolVolcanoAtmospheric sciencesStratosphereMicrowave Limb SounderEnvironmental scienceVulcanian eruptionSatelliteAtmospheric Infrared SounderSulfate aerosolClimatologyGeologyMeteorologyTropospherePhysics

Abstract

fetched live from OpenAlex

Abstract Decreases in stratospheric NO x associated with enhanced aerosol have been observed after large volcanic eruptions, for example, after the eruption of Mount Pinatubo in 1991. While the 1991 Mount Pinatubo eruption was the last large explosive eruption, recent studies have shed light on the impacts of moderate‐sized eruptions since the year 2000 on the global stratospheric aerosol budget. We use an ensemble of simulations from a coupled climate‐chemistry model to quantify and analyze changes in NO and NO 2 (NO x ), N 2 O 5 , HNO 3 , ClO, and ClONO 2 during periods of increased stratospheric volcanic aerosol concentrations since 2000. By using an ensemble approach, we are able to distinguish forced responses from internal variability. We also compare the model ensemble results to satellite measurements of these changes in atmospheric composition, including measurements from the Optical Spectrograph and Infrared Imaging Spectrometer on the Odin satellite and the Aura Microwave Limb Sounder. We find decreases in stratospheric NO x concentrations up to 20 hPa, consistent with increases in stratospheric HNO 3 concentrations. The HNO 3 perturbations also extend higher, up to 5 hPa, associated with periods of increased volcanic aerosol concentrations in both model simulations and observations, though correlations with volcanic aerosol are considerably higher in the model simulations. The model simulates increases in ClO at altitudes and magnitudes similar to the NO x reductions, but this response is below the detectable limit in the available observations (100 pptv). We also demonstrate the value of accounting for transport‐related anomalies of atmospheric trace gases by regression onto N 2 O anomalies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.559
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.254
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2019
Admission routes1
Has abstractyes

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