Antiferromagnetic coupling in copper(II)porphyrin dimers linked by copper(II) or palladium(II) ion
Bibliographic record
Abstract
The synthesis of porphyrin dimers linked by metal ions is described and the X-ray structure of two new dimers is presented. As previously shown for diamagnetic metal ions, strong electronic interactions between the individual subunits were observed. Antiferromagnetic coupling between copper(II)porphyrins linked by palladium(II) or copper(II) ions was studied by EPR and SQUID measurements. For the palladium(II)-linked dimer, the very small antiferromagnetic coupling was estimated by EPR measurements ([Formula: see text] <-1 cm[Formula: see text]. For the trinuclear-copper(II)-linked dimer, a large antiferromagnetic coupling between the copper(II) ions was measured. In this trinuclear compound, the linking copper(II) ion is used as a relay to increase the interaction between the two copper(II)porphyrins.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".