Complexation of UO<sub>2</sub>(CO<sub>3</sub>)<sub>3</sub><sup>4−</sup>with Mg<sup>2+</sup>at varying temperatures and its effect on U(<scp>vi</scp>) speciation in groundwater and seawater
Bibliographic record
Abstract
The ternary alkaline earth metal uranyl tricarbonate complexes, MnUO2(CO3)32n-4 (M = Mg and Ca), have been considered to be the major U(vi) species contributing to uranium mobility in natural water. Although MgUO2(CO3)32- can account for a substantial portion of U(vi) in a Mg2+-rich aqueous system and most processes regarding uranium are subjected to variable temperatures, chemical thermodynamic data for the prediction of the formation of MgUO2(CO3)32- at variable temperatures are still unknown. To fill the knowledge gap in the current chemical thermodynamic database, ultraviolet/visible (UV/Vis) absorption spectroscopy was employed to determine the formation constants (log K') of MgUO2(CO3)32- at varying temperatures of 10-85 °C in 0.5 mol kg-1 NaCl. The formation constants at infinite dilution, log K°, were obtained with specific ion interaction theory (SIT), and an increasing tendency of log K° with temperature was observed. Using calorimetric titration, the endothermic molar enthalpy of reaction (ΔrHm) of Mg2+ complexation with UO2(CO3)34- was determined at 25 °C. According to the chemical thermodynamic data obtained in this work, approximation models for the prediction of the temperature-dependent formation constant at a given temperature were examined and the constant enthalpy approximation with modification to the isoelectric reaction showed a satisfactory agreement with our experimental results. Finally, the effects of temperature on U(vi) speciation in Mg2+-rich groundwater and U(vi) extraction from seawater by amidoxime derivatives were examined. For the first time, this work provides important chemical thermodynamic data of MgUO2(CO3)32n-4 to assess the impact of temperature on U(vi) behaviour in groundwater and seawater.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".