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Record W2974608048

KINETICS, EQUILIBRIUM STUDIES ON REMOVAL OF IONIC DYES USING A NOVEL NONCONVENTIONAL ACTIVATED CARBON

2012· article· en· W2974608048 on OpenAlexvenueno aff
A. Agalya, P. N. Palanisamy, P. Sivakumar

Bibliographic record

VenueInternational Journal of Chemistry · 2012
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryActivated carbonKineticsMalachite greenEndothermic processAdsorptionPhysisorptionDiffusionCationic polymerizationLangmuir adsorption modelActivation energyLangmuirNuclear chemistryAnalytical Chemistry (journal)ChromatographyPhysical chemistryThermodynamicsOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

The feasibility of activated carbon prepared from Euphorbia Tirucalli wood using H3PO4 for the removal of Malachite Green (Cationic) and DirectBlue (Anionic) dyes was investigated. The effects of initial dye concentration, contact time, pH and temperature onto ETAC were studied.Equilibrium isotherms and kinetics were investigated and the experimental data fitted well with the Langmuir model. The maximum monolayeradsorption capacities of ETAC were found to be 181.81 mg/g and 138.88 mg/g for MG and DB respectively. The kinetic data obtained were analyzedusing pseudo-first order, pseudo-second order and intra particle diffusion models. Thermodynamic parameters were evaluated and suggesting thespontaneous and endothermic nature of physisorption. Activation energy for the adsorption of MG and DB were 12.1402 kJ/mole and 28.8484kJ/mole

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.920

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.311
Teacher spread0.272 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2012
Admission routes1
Has abstractyes

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