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Record W2976456586 · doi:10.1002/admt.201900569

Purple to Yellow Silicone Elastomers: Design of a Versatile Sensor for Screening Antioxidant Activity

2019· article· en· W2976456586 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Materials Technologies · 2019
Typearticle
Languageen
FieldChemical Engineering
TopicAnalytical Chemistry and Sensors
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of CanadaOtto Mønsteds FondVillum Fonden
KeywordsElastomerSiliconeAntioxidantPolymer scienceMaterials scienceSilicone ElastomersComposite materialChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Antioxidants play a key role in counteracting the adverse effects of oxidative stress in human organisms. Thus, there is a huge demand for the development of smart and convenient assays for the evaluation of antioxidant activity of synthetic and natural compounds, food samples, plant extracts, etc. The design of a solid‐state, flexible, and portable format of the traditional in vitro 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) radical test is reported. For the first time, purple DPPH radicals are physically immobilized into a silicone matrix by means of a facile and rapid process. The working principle of the resulting sensor is based on the colorimetric process that is associated with the redox reaction of DPPH radicals with antioxidants. When an antioxidant reacts with the sensor, a color change from purple to yellow can be perceived by the naked eye. The response of the sensor is investigated qualitatively and quantitatively toward food samples and selected antioxidants of different natures, and solubilized in different media. It is demonstrated that the DPPH silicone sensor is highly versatile and can be used as a ready‐to‐use sensor for direct colorimetric detection of antioxidants.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.058
Threshold uncertainty score0.705

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.253
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it