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Record W2979798227 · doi:10.1002/adfm.201905229

Bioinspired Graphene Oxide Membranes with Dual Transport Mechanisms for Precise Molecular Separation

2019· article· en· W2979798227 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Functional Materials · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicMembrane Separation Technologies
Canadian institutionsUniversity of Waterloo
FundersNational Key Research and Development Program of ChinaUniversity of WaterlooNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of China
KeywordsMembraneMaterials sciencePermeanceGrapheneFacilitated diffusionOxideEthylene oxideGas separationEthyleneSelectivityMoleculeMolecular dynamicsNanotechnologyChemical engineeringPermeationOrganic chemistryPolymerChemistryComputational chemistryComposite materialCopolymer

Abstract

fetched live from OpenAlex

Abstract The implementation of membrane technology to replace or combine with energy‐intensive cryogenic distillation for precise separation of ethylene/ethane mixture proves an extremely important yet highly challenging task. Inspired by the hierarchical structure and facilitated gas transport of biological membranes, a highly selective ethylene/ethane separation membrane is explored through the fixation of a silver ion carrier and the impregnation of ionic liquid within 2D nanochannels of graphene oxide laminate, where plenty of ethylene‐permeating in‐plane nano‐wrinkles and ethylene‐facilitated plane‐to‐plane nanochannels are constructed. By virtue of synergistic effects of molecular sieving and carrier‐facilitated transport, an unprecedented combination of high ethylene permeance (72.5 GPU) and superhigh ethylene/ethane selectivity (215) is achieved, out‐performing currently reported advanced membranes. Moreover, molecular dynamics simulations verify a favorable membrane nanostructure for fast and selective transport of ethylene molecules. This bioinspired approach with dual transport mechanisms may open novel avenues to the design of high‐performance membranes for precise molecular separation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.223
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it