A low temperature pyrolytic route to amorphous quasi-hexagonal boron nitride from hydrogen rich (NH<sub>4</sub>)<sub>3</sub>Mg(BH<sub>4</sub>)<sub>5</sub>
Bibliographic record
Abstract
Pure amorphous quasi-hexagonal boron nitride with minute amounts of amorphous quasi-cubic form was obtained via thermal decomposition of a novel tri-ammonium magnesium penta-borohydride precursor, (NH4)3Mg(BH4)5, in the temperature range of 220-250 °C, which is significantly lower than 1000-1500 °C applied in industrial approaches. The (NH4)3Mg(BH4)5 precursor, the most hydrogen rich mixed-cation borohydride salt known to date (21 wt% H), was prepared via low temperature high-energy dry disc-milling. The compound adopts a tetragonal I4/mcm unit cell isostructural with Rb3Mg(BH4)5 and Cs3Mg(BH4)5. The multi-step thermal decomposition yields hydrogen contaminated with B2H6 and borazine volatiles. The solid residue rinsed with water corresponds to amorphous boron nitride of high purity as evidenced by 11B MAS NMR, PXRD, FTIR and EDX analyses.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.000 |
| Meta-epidemiology (narrow) | 0.002 | 0.002 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.001 | 0.010 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".