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Record W3011479031 · doi:10.1088/2053-1591/ab8160

Synthesis of praseodymium-and molybdenum- sulfide nanoparticles for dye-photodegradation and near-infrared deep-tissue imaging

2020· article· en· W3011479031 on OpenAlexaff
Ye Wu, Pengfei Ou, Jun Song, Ling Zhang, Yingcheng Lin, Pengfei Song

Bibliographic record

VenueMaterials Research Express · 2020
Typearticle
Languageen
FieldMaterials Science
TopicQuantum Dots Synthesis And Properties
Canadian institutionsMcGill University
Fundersnot available
KeywordsPhotodegradationRhodamine BRhodamineNanoparticlePhotochemistryChemistryMaterials scienceFluorescenceFluorescence spectroscopyQuenching (fluorescence)Sodium sulfideNuclear chemistryPhotocatalysisInorganic chemistryNanotechnologyOrganic chemistryOptics

Abstract

fetched live from OpenAlex

Abstract Development of nanoparticles with multi-functionalities is of great importance. In this study, praseodymium sulfide (Pr 2 S 3 ) and molybdenum sulfide (MoS 2 ) nanoparticles were synthesized. The structural, morphological and optical properties of the as-obtained products were investigated by XRD, XPS, TEM, UV–vis-NIR spectroscopy, and photoluminescence spectroscopy. Pr 2 S 3 is found to be used in selective photodegradation of fluorescein sodium salt. MoS 2 can be utilized for selective photodegradation of rhodamine B. In the mixture of rhodamine B, fluorescein sodium salt and rhodamine 6 G, most of rhodamine B and part of fluorescein sodium salt are optically degraded by Pr 2 S 3 . In the mixture of rhodamine B, fluorescein sodium salt and rhodamine 6 G, part of fluorescein sodium salt and most of rhodamine B is degraded by MoS 2 . Moreover, they emit near-infrared fluorescence (800–1100 nm) when excited by the 785 nm light. Deep tissues imaging with high-contrast is shown, utilizing a nanoparticle-filled centrifuge tube covered with animal tissues (pig Bacon meat). Maximum imaging depth below the tissue surface of 1 cm is achieved. Our work provides a rapid yet efficient procedure to make nanoparticles for dual-application-potential in dye-photodegradation and near-infrared deep tissue imaging.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.001

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.062
GPT teacher head0.321
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2020
Admission routes1
Has abstractyes

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