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Record W3012667075

Sulfur Diffusion in Basaltic Melts

2004· article· fr· W3012667075 on OpenAlex
C. Freda, Don R. Baker, Piergiorgio Scarlato

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAGUSM · 2004
Typearticle
Languagefr
FieldMaterials Science
TopicGlass properties and applications
Canadian institutionsMcGill University
Fundersnot available
KeywordsSulfurDiffusionAnhydrousChemistryBasaltSulfideThermal diffusivityMineralogyAnalytical Chemistry (journal)ThermodynamicsGeologyGeochemistryEnvironmental chemistryOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

Abstract We measured the diffusion coefficients of sulfur in two different basaltic melts at reduced conditions (i.e., in the sulfide stability field), temperatures from 1225°C to 1450°C, pressures of 0.5 and 1 GPa, and water concentrations of 0 and 3.5 wt%. Although each melt is characterized by slightly different sulfur diffusion coefficients, the results can be combined to create a general equation for sulfur diffusion in anhydrous basalts: D = 2.19 × 10 − 4 exp ⁡ ( − 226.3 ± 58.3 R T ) where D is the diffusion coefficient in m2s-1, the activation energy is in kJ mol-1, R is the gas constant, and T is the temperature in K. Sulfur diffusion in basalts with 3.5 wt% water is a factor of three to seven higher than in anhydrous melts and can be described by: D = 5.91 × 10 − 7 exp ⁡ ( − 130.8 ± 82.6 R T ) At the conditions of this study the pressure does not measurably affect sulfur diffusion. Sulfur diffusion in dry basaltic melts is one order of magnitude higher than sulfur diffusion in dry andesitic and dacitic melts, whereas sulfur diffusion in hydrous basaltic and andesitic melts is within the same order of magnitude. When compared to the diffusivity of other volatile species in nominally dry basaltic melts, sulfur diffusion appears to be two times lower than CO2 diffusion and two orders of magnitude lower than H2O diffusion.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.436
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.244
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it