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Record W3023219157 · doi:10.1021/ef9003889

Chemical-Looping Gasification of Biomass for Hydrogen-Enriched Gas Production with In-Process Carbon Dioxide Capture

2009· article· en· W3023219157 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnergy & Fuels · 2009
Typearticle
Languageen
FieldEngineering
TopicChemical Looping and Thermochemical Processes
Canadian institutionsNova Scotia Department of AgricultureDalhousie University
Fundersnot available
KeywordsSorbentSyngasBiomass (ecology)Wood gas generatorFluidized bedHydrogen productionChemical looping combustionCarbon dioxideRaw materialWaste managementIntegrated gasification combined cycleCalcium loopingSawdusttar (computing)Environmental scienceFluidizationChemical engineeringPulp and paper industryChemistryHydrogenCoalAdsorptionEngineering

Abstract

fetched live from OpenAlex

The research presents an innovative idea of developing a continuous H 2 production process employing fluidized-bed technology from agricultural biomass with in situ CO 2 capture and sorbent regeneration. Novelty of the process lies in the generation of relatively pure H 2 from biomass with CO 2 as a byproduct using steam as the gasifying agent. Another unique feature of the process is internal regeneration of the sorbent, fouled in the gasifier. Thus, the technology will serve the twin purpose of regenerating the sorbent and generation of N 2 -free H 2 and CO 2 . This work reports theoretical energy analysis and experimental investigation of the process. The system efficiency of the chemical-looping gasification process at an ideal scenario is found to be 87.49% with biomass as fuel. A sensitivity analysis for system efficiency is also conducted by varying carbon-capture and regeneration efficiencies. The experiments conducted in a batch-type fluidized-bed steam gasifier using CaO as the sorbent shows a 71% concentration of H 2 and nearly 0% concentration of CO 2 in the product gas when sawdust was used as the feedstock. In a separate test using a circulating fluidized-bed reactor as the regenerator, a 40% regeneration of CaO is also achieved at a calcination temperature of 800 °C.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.683

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.209
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it