MétaCan
Menu
Back to cohort
Record W3024897100 · doi:10.1021/acs.est.0c01898

Screening New Persistent and Bioaccumulative Organics in China’s Inventory of Industrial Chemicals

2020· article· en· W3024897100 on OpenAlexaff
Xianming Zhang, Xiangfei Sun, Ruifen Jiang, Eddy Y. Zeng, Elsie M. Sunderland, Derek C. G. Muir

Bibliographic record

VenueEnvironmental Science & Technology · 2020
Typearticle
Languageen
FieldEnvironmental Science
TopicPer- and polyfluoroalkyl substances research
Canadian institutionsEnvironment and Climate Change CanadaUniversity of Toronto
Fundersnot available
KeywordsBioaccumulationEnvironmental scienceChinaEnvironmental chemistryPersistent organic pollutantChemistryWaste managementPollutantEngineeringGeographyOrganic chemistry

Abstract

fetched live from OpenAlex

Over a third of the world's annual chemical production and sales occur in China. Thus, knowledge of the properties of the substances produced and emitted there is important from a global perspective. The chemical Inventory of Existing Chemical Substances of China (IECSC) lists over 45 000 chemicals. When compared to the North American and European chemical inventories, 6916 substances were found to be unique to the IECSC. We retrieved structural information for 14 938 organic chemicals in the IECSC and determined their overall environmental persistence , bioaccumulation factor (BAF), and long-range transport potential (transfer efficiency) using in silico approaches with the goal of identifying new chemicals with properties that might lead to global contamination issues. Overall, 10% of the 14 938 chemicals were unique to the IECSC and their environmental persistence and BAF were statistically higher than the values for the rest of the IECSC chemicals. We prioritized 27 neutral organic compounds predicted to have prolonged environmental persistence, and high potential for bioaccumulation and long-range transport when compared with polychlorinated biphenyls as a benchmark. We also identified 69 organofluorine compounds with three or more perfluorinated moieties, unique to the IECSC. Screening approaches and results from this study help to identify and prioritize those to be considered in further environmental modeling and monitoring assessments.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.230
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.003
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.038
GPT teacher head0.259
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations59
Published2020
Admission routes1
Has abstractyes

Explore more

Same venueEnvironmental Science & TechnologySame topicPer- and polyfluoroalkyl substances researchFrench-language works237,207