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Record W3033641257 · doi:10.1002/anie.202007036

Inside Back Cover: Crystal Engineering of Room Temperature Phosphorescence in Organic Solids (Angew. Chem. Int. Ed. 25/2020)

2020· paratext· en· W3033641257 on OpenAlex
Ehsan Hamzehpoor, Dmitrii F. Perepichka

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie International Edition · 2020
Typeparatext
Languageen
FieldMaterials Science
TopicLuminescence and Fluorescent Materials
Canadian institutionsMcGill University
Fundersnot available
KeywordsPhosphorescenceSteric effectsQuantum yieldLuminescenceCrystal engineeringFluorescenceCover (algebra)Yield (engineering)PhotochemistryChemistryMaterials scienceNanotechnologyCrystal structureCrystallographyStereochemistryOptoelectronicsSupramolecular chemistryPhysicsOptics

Abstract

fetched live from OpenAlex

The molecular packing of organic luminogens governs their photophysical behavior. In their Communication on page 9977, E. Hamzehpoor and D. F. Perepichka report a series of highly emissive azatriangulenetrione (TANGO) solids whose luminescence properties are controlled by the size of the substituents. The co-alignment of carbonyl groups in sterically unencumbered TANGO derivatives leads to room-temperature phosphorescence (triplet emission) with a quantum yield of up to 42 %, while the approximately 60° rotation induced by bulky tert-butyl groups results in an almost pure fluorescence.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.268
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0320.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.229
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it