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Record W3036436261 · doi:10.1002/sia.6830

XPS and TOF‐SIMS applied to the study of ancient artifacts: Further studies on Alexandrian tetradrachms from the time of the Julio‐Claudian dynasty

2020· article· en· W3036436261 on OpenAlexaff
R. N. S. Sodhi, Peter Brodersen, Cristiana Zaccagnino

Bibliographic record

VenueSurface and Interface Analysis · 2020
Typearticle
Languageen
FieldArts and Humanities
TopicCultural Heritage Materials Analysis
Canadian institutionsQueen's UniversityUniversity of Toronto
Fundersnot available
KeywordsEmperorX-ray photoelectron spectroscopyQueen (butterfly)Time of flightMass spectrometryIdentification (biology)Analytical Chemistry (journal)ArtMaterials scienceChemistryAncient historyHistoryEnvironmental chemistryEngineeringChemical engineeringChromatography

Abstract

fetched live from OpenAlex

Two tetradrachms from the Diniacopoulos collection housed at Queen's University are the subject of this study. Previously, a protocol had been developed for a coin of the Emperor Claudius from the same collection, which showed that a combination of Time‐of‐Flight Secondary Ion Mass Spectrometry (TOF‐SIMS), Energy Dispersive X‐ray Spectroscopy (EDX), and X‐ray Photoelectron Spectroscopy (XPS) could provide information and identify areas of interest for additional analysis, thereby minimizing the amount of damage incurred. This is now applied to two more tetradrachms issued by the same mint and dated respectively to the time of Tiberius (14–37 AD) and Nero (54–68 AD). Preliminary results have indicated both differences and similarities between these coins and that from the time of Claudius. By comparing these results, it is hoped that information as to how the coins were made can be elucidated, shedding light on the different components and composition of the alloys produced in the same mint but at different time periods. Moreover, the detection and the identification of corrosion products, along with understanding what restorations methods may have been applied in the past, can guide conservators to determine what conservation treatment and preservation strategies are most appropriate for these antiquities.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Qualitative · Consensus signal: Qualitative
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.251
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designQualitative
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2020
Admission routes1
Has abstractyes

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