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Traceability in isotope ratio measurements: the role of data analysis

2020· article· en· W3083905797 on OpenAlexaff
Juris Meija

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldEnvironmental Science
TopicIsotope Analysis in Ecology
Canadian institutionsNational Research Council CanadaMétis National Council
Fundersnot available
KeywordsTraceabilityComparabilityIsotopeIsotope analysisChemistryEnvironmental scienceComputer scienceStatisticsGeologyMathematicsNuclear physicsPhysics

Abstract

fetched live from OpenAlex

Isotope ratios offer countless applications but almost as a rule precision measurements are required. Making use of such measurements involves comparison of the results between the laboratories which, in turn, requires international primary standards. Much less appreciated is the role of data analysis and measurement models. This presentation will feature a variety of examples of stable isotope ratio measurements, including light and heavy elements with examples from the redefinition of the kilogram, lead-lead dating, and carbon isotope delta reference scales, showing that choices on how we interpret and model our measurements can affect the traceability and comparability of isotope ratio measurements. The challenge is therefore for the analysts to recognize data analysis practices as a natural part of the measurement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.191
metaresearch head score (Gemma)0.341
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesMetaresearch
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.191
Threshold uncertainty score0.997

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.1910.341
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0070.007
Science and technology studies0.0030.019
Scholarly communication0.0220.028
Open science0.0060.009
Research integrity0.0040.009
Insufficient payload (model declined to judge)0.0030.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.054
GPT teacher head0.273
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2020
Admission routes1
Has abstractyes

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