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Record W3109633487 · doi:10.1002/cjce.23973

Effect of temperature and reaction atmosphere on nitric oxide emission during a char grate‐fired process in local flue gas recirculation

2020· article· en· W3109633487 on OpenAlexvenueno aff
Biying Yang, Jianmin Gao, Li Xu, Jie Xu, Qian Du, Fengan Zhang, Lei Chen, Guangbo Zhao, Shaohua Wu

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicThermochemical Biomass Conversion Processes
Canadian institutionsnot available
FundersNational Natural Science Foundation of China
KeywordsFlue gasCharNOxNitrogen oxideNitrogenChemistryOxygenFlueWaste managementAtmosphere (unit)Flux (metallurgy)CoalEnvironmental chemistryEnvironmental engineeringEnvironmental scienceCombustionOrganic chemistryMeteorology

Abstract

fetched live from OpenAlex

Abstract Local flue gas recirculation (LFGR) is an effective technology for reducing nitrogen oxide (NOx) emissions from coal‐fired industrial boilers. The temperature and reaction atmosphere changes when flue gas is recycled, thereby affecting both the grate‐fired process and NOx emission. In this paper, the boundary of LFGR was simulated by changing the experimental parameters. On a small‐scale one‐dimensional fixed‐bed system, the effects of temperature, O2 flux, and CO, CO2, and recycled NO concentrations on oxidation‐reduction layering and char nitrogen conversion during the char grate‐fired process were studied. The effect of temperature and recycled flue gas components on nitric oxide (NO) emissions during the char grate‐fired process was then analyzed based on the mass proportion of oxygen‐absent and oxygen‐present parts. The results show that, with the introduction of recycled flue gas, increasing the temperature will also increase the reduction layer mass and proportion, and, subsequently, inhibit NO emissions; increasing the O2 flux will reduce the reduction layer proportion and subsequently promote NO emissions; increasing the CO and CO2 concentrations will reduce the NO emitted from the oxidation layer, yet has limited effects on the entire char bed; and recycled NO will significantly reduce the NO emissions. The effect of LFGR‐induced changes in temperature and reaction atmosphere on NO emissions can be ascribed to the negative effect of the increase in O2 flux and the positive effect of the increase in temperature and CO, CO2, and recycled NO concentrations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.169
Teacher spread0.165 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2020
Admission routes1
Has abstractyes

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