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Record W3110562003 · doi:10.1002/cjce.23963

Optimization of semi‐pulsatile liquid‐liquid extraction operations in milli‐channels

2020· article· en· W3110562003 on OpenAlexvenueno aff
Abir Chakravorty, Abhradeep Maitra, Aditya Bandopadhyay

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsnot available
Fundersnot available
KeywordsMass transferPulsatile flowExtraction (chemistry)AmplitudeMechanicsFlow (mathematics)Continuous phase modulationSlug flowMaterials scienceVolumetric flow rateSuperficial velocityAnalytical Chemistry (journal)Phase (matter)Aqueous two-phase systemLiquid–liquid extractionChromatographyChemistryTwo-phase flowPhysicsOpticsElectronic engineering

Abstract

fetched live from OpenAlex

Abstract The work in this manuscript presents liquid‐liquid extraction augmentation and optimization due to flow pulsations on a continuous flow. The mass transfer is achieved via a transfer species (acetic acid) that diffuses in the aqueous phase (water), which is in a continuous flow, from the organic phase (toluene), exhibiting pulsed flow pattern. It is observed through experiments that the incorporation of pulsation leads to enhanced extraction/mass transfer compared to continuous flows. Also, an increase of the pulsation parameters, such as amplitude and frequency, increases the mass transfer, but when the process is evaluated in terms of economy, it is found that the rate of extraction per unit power is maximum for moderate frequencies and amplitudes. Based on the experiments, a Linton and Sherwood‐like correlation for determining extracted concentration at the exit of the test section in semi‐pulsatile flow conditions is proposed. During the course of experiments, it is found that the flow pattern changes from dispersed‐type flow pattern of the organic phase to slug and then slug dispersed with an increase of superficial velocity of toluene, at a particular superficial velocity of the water. Also, the total power consumed during the extraction process increases with an increase in the product of amplitude and frequency. With the experimental approach presented in this paper, one will be able to optimize semi‐pulsatile liquid‐liquid mass transfer operations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.212
Teacher spread0.200 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations1
Published2020
Admission routes1
Has abstractyes

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