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Record W3113118054 · doi:10.1002/cjce.24001

Closed form solutions of convection‐diffusion mechanisms in two dimensions for <scp> H <sub>2</sub> </scp> separation from ( <scp> H <sub>2</sub> </scp> / <scp> CO <sub>2</sub> </scp> ) mixture at room temperature

2020· article· en· W3113118054 on OpenAlexvenueno aff
Joydeb Mukherjee, Ankita Bose, Aniruddha B. Pandit, Nandini Das

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsnot available
FundersDepartment of Science and Technology, Republic of the PhilippinesMinistry of Science and Technology
KeywordsPermeationHydrogenMembraneChemistryDiffusionAnalytical Chemistry (journal)ChromatographyChemical engineeringThermodynamicsOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

Abstract Studies pertinent to the hydrogen based clean energy systems have seen a significant surge in this decade in order to meet the ever‐increasing demand for energy in an environmentally sustainable way. In order to harness hydrogen from available sources, development and characterization of zeolite membranes with high hydrogen selectivity is of pivotal importance. In this study, a sonication based hydrothermal technique is used for the synthesis of Deca‐Dodecasil‐rhombohedral (DDR) zeolite membrane. Permeation tests of single gas and mixture of gases were conducted by using an in‐house designed permeation cell. For the single gas permeation test, permeate flux was calculated using soap bubble flow meter under varying feed pressure (98‐392 kPa) at 303 K. For the mixed gas permeation test, separation selectivity was measured by using gas chromatography. A mathematical model was developed in order to predict the total volume flux of hydrogen. A simple, two‐dimensional parameter model was developed to simulate the steady state permeate flux, permeate and retentate streams, and the permeate concentrations for both H 2 and CO 2 . Fourier transform was found to give the best prediction for the axial diffusion coefficient, as well as the concentration distribution of both the components, (H 2 and CO 2 ). A good agreement was found between the observed and the calculated values for total volumetric permeate flux .The deviation between experimentally obtained results with the predicted values based on the analytical model was found to be as low as ±7%, ensuring adequate reliability of the proposed analytical model.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.207
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2020
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical EngineeringSame topicZeolite Catalysis and SynthesisFrench-language works237,207