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Record W3122354834 · doi:10.1007/s12598-020-01659-z

Plasmonic photo‐assisted electrochemical sensor for detection of trace lead ions based on Au anchored on two‐dimensional g‐C <sub>3</sub> N <sub>4</sub> /graphene nanosheets

2021· article· en· W3122354834 on OpenAlexaff
Jiayue Hu, Zhi Li, Chunyang Zhai, Jun-Feng Wang, Lixi Zeng, Mingshan Zhu

Bibliographic record

VenueRare Metals · 2021
Typearticle
Languageen
FieldChemistry
TopicElectrochemical Analysis and Applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMaterials scienceGrapheneDetection limitGraphitic carbon nitrideX-ray photoelectron spectroscopyPlasmonSurface plasmon resonanceAnalytical Chemistry (journal)OptoelectronicsNanoparticleNanotechnologyPhotocatalysisChemical engineering

Abstract

fetched live from OpenAlex

Abstract In this paper, a plasmonic photo‐assisted electrochemical sensor, Au anchored on two‐dimensional (2D) graphitic carbon nitride (g‐C 3 N 4 )/reduced graphene oxide (rGO) nanosheets (Au/g‐C 3 N 4 /rGO), was facile fabricated. The morphology and structure of the composite are characterized by transmission electron microscope, X‐ray photoelectron spectroscopy, X‐ray diffraction and ultraviolet–visible spectrophotometer (UV–Vis). Based on the semiconductor of g‐C 3 N 4 and optical properties of surface plasmon resonance for Au, the as‐prepared Au/g‐C 3 N 4 /rGO showed high sensitivity for the detection of trace lead ion [Pb(II)] by differential pulse anodic stripping voltammetry in the presence of visible light illumination. Under optimized conditions, the limit of detection (signal‐to‐noise ratio ( S / N ) = 3) Pb(II) detection can be low to 0.1 nmol·L −1 . In addition, the interference research and real soil sample detection were measured to confirm the possibility of practical applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.240
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations53
Published2021
Admission routes1
Has abstractyes

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