Variables of the Analytical Electrochemical Data Acquisition for Boron Subphthalocyanines
Bibliographic record
Abstract
Abstract The electrochemical behavior of boron subphthalocyanines (BsubPcs) has been investigated using cyclic voltammetry in the presence of various solvents, internal standards, supporting electrolytes, working electrodes, and sweep voltage scan rates. We have focused on halogenated BsubPcs (Cl−Cl6BsubPc, Cl−Cl12BsubPc, F−F6BsubPc, F−F12BsubPc) and a non‐halogenated baseline (Cl−BsubPc). Halogenated BsubPcs are of interest to the field due to their promising advances as organic electronic materials for applications based on redox or electron transfer processes. We had pre‐established a standard operating procedure (SOP) for electrochemical data acquisition, but it was timely to consider alternative variables, their impact on the electrochemical data and re‐establish an alternative SOP. We observed modest shifts (up to 49 mV) of the BsubPc redox potentials when changing the internal standard, working electrode and/or the electrolyte concentration. In scan rate range between 20 and 250 mV s−1, the peak (ir)reversibility for F−F6BsubPc and F−F12BsubPc remained unchanged and the electron transfers at the surface electrode remained diffusion‐controlled.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.005 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".