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Eucalyptus Bark as Source of Bio-oil or Phenolic Compounds

2021· article· en· W3129182227 on OpenAlexaff
Alcides Lopes Leão, Ivana Cesarino, Otávio Augusto Titton Dias, Mirela Bertin Carnietto, Mohini Sain

Bibliographic record

VenueCurrent Applied Polymer Science · 2021
Typearticle
Languageen
FieldMaterials Science
TopicNatural Fiber Reinforced Composites
Canadian institutionsUniversity of Toronto
FundersFundação de Amparo à Pesquisa do Estado de São Paulo
KeywordsPyrolysisPulp and paper industryBiomass (ecology)Materials scienceThermogravimetric analysisRaw materialPhenolsChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Background: Eucalyptus bark and scraps are generated in the production of mediumdensity fiberboard (MDF). An approach aiming to add value to such wastes was studied, following the concepts of circular economy and biomass cascade strategy. Bio-oil and phenolic resin were produced by pyrolysis from two types of biomass, Eucalyptus bark and MDF waste. As is well known, conventional phenolic resins are normally obtained from fossil resources. These products were obtained from the pyrolysis of two types of biomass to reduce environmental waste and dependence on petroleum-based products. Objective: The main objective of the present study was to produce phenolic resin from Eucalyptus wastes, aiming to reduce the fossil dependence on conventional resins used in the production line of MDF. Methods: Fast pyrolysis and slow pyrolysis were employed for bio-oil and phenolic resin production. The bio-oil and resins were characterized with standard lab analyses for their physicochemical properties, while their thermal properties were studied via thermogravimetric analysis (TGA). Results: The shear strength of the lap internal bonding of the phenolic resin binders with 19.8% of bio-oil was 2.09, 1.34, and 1.63 MPa under dry, boiler, and soaked conditions, respectively, which was acceptable for panel fabrication and can represent a significant saving in terms of fossil resins and cost reduction. Discussion: According to the results, 1 g medium fraction of bio-oils was equivalent to 1.35 g of conventional phenols, indicating those bio-oils as phenolic structures that could be used as binders. The bio-oil yields for bark and MDF were 40.9 and 25.1, respectively, which indicate a potential for replacing the conventional fossil-based phenolic resin. Conclusion: The results revealed the possibility of replacing conventional fossil-based chemicals with phenolic resin from renewable resources with similar overall properties, replacing about 1/3 of the conventional resin.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.927

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.282
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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