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Record W3161842680 · doi:10.1111/ggr.12385

Chemical and Mineralogical Mapping of Platinum‐Group Element Ore Samples Using Laser‐Induced Breakdown Spectroscopy and Micro‐X‐Ray Fluorescence

2021· article· en· W3161842680 on OpenAlex
Nessrine Mohamed, Kheireddine Rifaï, Samira Selmani, Marc Constantin, François R. Doucet, Lütfü Ç. Özcan, Mohamad Sabsabi, François Vidal

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueGeostandards and Geoanalytical Research · 2021
Typearticle
Languageen
FieldEngineering
TopicLaser-induced spectroscopy and plasma
Canadian institutionsNational Research Council CanadaInstitut National de la Recherche ScientifiqueUniversité Laval
FundersNatural Sciences and Engineering Research Council of CanadaMitacs
KeywordsLaser-induced breakdown spectroscopyPlatinum groupChalcopyritePentlanditeMineralogySulfideMineralPyritePyrrhotiteSilicate mineralsAnalytical Chemistry (journal)Sulfide mineralsGeologyMineral redox bufferSilicateChemistrySpectroscopyMaterials scienceGeochemistryMetallurgyPlatinumEnvironmental chemistryCopper

Abstract

fetched live from OpenAlex

Standard techniques for geochemical and mineralogical characterisation are time‐consuming, they can involve significant sample preparation and they are prone to error. The aim of this work is to show how the emerging fast laser‐induced breakdown spectroscopy (LIBS) technique can be valuable for mineral exploration. For this purpose, the well‐established micro‐X‐ray fluorescence (µ‐XRF) technique was used to validate the LIBS data. Two ore samples from the platinum‐group elements (PGE) Lac des Îles mine (Ontario, Canada) were analysed both by LIBS and µ‐XRF. The fast mineralogical and elemental mapping provided by LIBS allowed the identification of four major silicate phases (chlorite, bytownite, actinolite, hornblende) and four minor sulfide phases (Pd‐bearing pentlandite, chalcopyrite, pyrrhotite, pyrite). Multi‐element chemical mapping and mineral characterisation using µ‐XRF corroborated the LIBS analyses for the composition, distribution and abundance of minerals in PGE ore samples. These findings demonstrate the ability of the LIBS technique to perform direct fast high‐resolution mapping of the chemical and mineralogical composition of PGE ore samples. This work highlights the advantages of LIBS for this application of being much faster and more sensitive to trace elements (e.g., Pd), as well as to low atomic number elements.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.076
Threshold uncertainty score0.917

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.054
GPT teacher head0.325
Teacher spread0.271 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it