Dual‐Active‐Center of Polyimide and Triazine Modified Atomic‐Layer Covalent Organic Frameworks for High‐Performance Li Storage
Why this work is in the frame
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Bibliographic record
Abstract
Abstract Covalent organic frameworks (COFs) have received great attention as electrode materials in the lithium‐ion batteries due to their exceptional crystallinity, easily chemical modification, and adjustable porous distribution. However, their practical application remains hindered by the insufficient Li + active sites and long ion diffusion in the bulk materials. To tackle those issues, combining the virtues of high stable skeleton structure of large molecular, atomic‐layer thickness feature, and multi‐active sites, a novel atomic‐layer COF cathode (denoted as E‐TP‐COF) with a dual‐active‐center of CO and CN group is developed. The atomic‐layer thick structure improves the capturing and diffusion of Li‐ion. Both active sites of CN and CO groups generate more capacity. The large molecular structure avoids the dissolubility challenge in electrolytes. As a result, the lithium‐ion batteries assembled with E‐TP‐COF delivers a high initial capacity of 110 mAh g −1 with a high capacity retention of 87.3% after 500 cycles. Furthermore, the Li + diffusion mechanism is also confirmed through in(ex) situ technology and density functional theory calculation in detailing. This new strategy may exploit an important application of COFs in electrochemical energy storage and conversion.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it