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Record W3175692320 · doi:10.1515/pac-2017-1002

Interpretation and use of standard atomic weights (IUPAC Technical Report)

2021· article· en· W3175692320 on OpenAlexaff
Adriaan M. H. van der Veen, Juris Meija, Antonio Possolo, David Brynn Hibbert

Bibliographic record

VenuePure and Applied Chemistry · 2021
Typearticle
Languageen
FieldChemistry
TopicChemical Thermodynamics and Molecular Structure
Canadian institutionsNational Research Council Canada
FundersIstituto Nazionale di Ricerca MetrologicaUniversity of East AngliaRice UniversityCancer Prevention and Research Institute of Texas
KeywordsAtomic massChemistryPropagation of uncertaintyChemical nomenclatureStandard uncertaintyMeasurement uncertaintyAtomic numberInterpretation (philosophy)Statistical physicsStatisticsAtomic physicsPhysicsMathematicsComputer science

Abstract

fetched live from OpenAlex

Abstract Many calculations for science or trade require the evaluation and propagation of measurement uncertainty. Although relative atomic masses (standard atomic weights) of elements in normal terrestrial materials and chemicals are widely used in science, the uncertainties associated with these values are not well understood. In this technical report, guidelines for the use of standard atomic weights are given. This use involves the derivation of a value and a standard uncertainty from a standard atomic weight, which is explained in accordance with the requirements of the Guide to the Expression of Uncertainty in Measurement. Both the use of standard atomic weights with the law of propagation of uncertainty and the Monte Carlo method are described. Furthermore, methods are provided for calculating uncertainties of relative molecular masses of substances and their mixtures. Methods are also outlined to compute material-specific atomic weights whose associated uncertainty may be smaller than the uncertainty associated with the standard atomic weights.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.023
metaresearch head score (Gemma)0.051
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.023
Threshold uncertainty score0.120

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0230.051
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0100.008
Science and technology studies0.0020.002
Scholarly communication0.0050.003
Open science0.0050.002
Research integrity0.0020.003
Insufficient payload (model declined to judge)0.0130.015

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.221
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2021
Admission routes1
Has abstractyes

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