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Record W3183271349 · doi:10.1002/aelm.202100460

Osmium‐ and Cobalt‐Terpyridine‐Based Electrochromic Devices for “Smart” Signage Application: The Effect of Lighting on Color Perception

2021· article· en· W3183271349 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Electronic Materials · 2021
Typearticle
Languageen
FieldMaterials Science
TopicTransition Metal Oxide Nanomaterials
Canadian institutionsOntario Tech University
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of CanadaCanada Foundation for Innovation
KeywordsElectrochromismMaterials scienceOptoelectronicsElectrochromic devicesLight-emitting diodeIndium tin oxideTerpyridineElectrodeNanotechnologyThin filmMetalChemistry

Abstract

fetched live from OpenAlex

Abstract Modern electrochromic devices (ECDs) have found a wide range of applications, which are not limited to the traditional design of “smart” windows and self‐dimming mirrors. Novel cutting‐edge applications in optoelectronics and particularly in low‐energy displays and “smart” signage require electrochromic materials (ECMs) that demonstrate significant changes in optical density, fast switching times, and color differences between the colored and bleached states that are visible to the naked eye. Here ECMs that are designed by the chemical deposition of electrochromic Co(II) and Os(II) complexes and their mixture on surface‐enhanced support fabricated by screen printing of indium–tin oxide (ITO‐50) nanoparticles are presented on an ITO/glass substrate. The oxidation state of the metal complexes is reversibly addressed by voltage switching between −1 and +3 V. Further assembly of the ECMs and ITO/glass counter electrode using gel electrolyte results in solid‐state ECDs. The changes in optical properties of these ECDs induced by the metal oxidation state alteration are tracked by recording UV–vis spectra. Moreover, here color differences (CDs) and changes in luminance of ECDs (Δ L ) in the colored and bleached state are compared when illuminated with light‐emitting diodes (LEDs) of different colors.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.931

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.247
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it