Thiol-Lactam Initiated Radical Polymerization (TLIRP): Scope andApplication for the Surface Functionalization of Nanoparticles
Bibliographic record
Abstract
: Controlled polymerization techniques make the possible fabrication of polymers with desired molecular weights, narrow dispersity, and tailor-making of advanced hybrid materials. Thiol- Lactam Initiated Radical Polymerization (TLIRP) was introduced in 2002 and developed during the last two decades. The thiol/lactam combination enables one to generate radicals that can initiate the polymerization of vinyl-based monomers. The study of the mechanism and kinetics of TLIRP revealed the characteristics of living polymerization for TLIRP. Moreover, TLIRP has been used successfully for the synthesis of homopolymers, block copolymers, and statistical copolymers with polydispersity below 2.0. Especially, TLIRP provides a very straightforward method for grafting polymer brushes on the surface of nanoparticles. We review herein the systems developed for TLIRP and their applications for macromolecular engineering, emphasizing the surface functionalization of nanoparticles via the grafting-from approach.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".