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Assessing and predicting phosphorus phytoavailability from sludge incineration ashes

2021· article· en· W3201762124 on OpenAlexafffundabout
Claude-Alla Joseph, Lotfi Khiari, Jacques Gallichand, Ned Beecher

Bibliographic record

VenueChemosphere · 2021
Typearticle
Languageen
FieldEnvironmental Science
TopicPhosphorus and nutrient management
Canadian institutionsUniversité LavalAgriculture and Agri-Food Canada
FundersMinistry of Environment and Sustainable DevelopmentNatural Sciences and Engineering Research Council of CanadaQuébec Ministère du Développement Durable, de l’Environnement et de la Lutte Contre les Changements Climatiques
KeywordsFertilizerLoamPhosphorusBioavailabilityExtraction (chemistry)IncinerationChemistrySolubilityEnvironmental scienceSewage sludgeAmmonium oxalateEnvironmental chemistrySoil waterAgronomyPulp and paper industryEnvironmental engineeringWaste managementSewage treatmentSoil scienceChromatography

Abstract

fetched live from OpenAlex

Incineration of municipal sludge and agri-food by-products generates large quantities of ash that can be used in agriculture as phosphorus fertilizer. The fertilizing potential of sludge incineration ash (SIA) from 12 cities in Canada and the United States was tested in a greenhouse experiment against a synthetic fertilizer (TSP: triple superphosphate), a natural fertilizer (RP: rock phosphate), and a control without any P fertilizer. Two soil types were used: clay and sandy loam. A reliable a priori indicator of SIA P bioavailability was determined using the random forest method. SIA application increased ryegrass P uptake. The SIA relative P effectiveness (RPE), compared to the TSP, varied from 5.1% to 46.2% depending on the sludge origin and P solubility. SIA RPE was greater than RP for the clay soil but similar for the sandy loam soil. The neutral ammonium citrate (NAC) extraction, sometimes inappropriately used to characterize P availability of sludge and by-products, explained only 53% of the RPE variation. The random forest analysis showed that the oxalate extraction (Al, P, and Fe) is a better indicator (R2 = 0.94) of relative availability of SIA than the NAC P solubility (R2 = 0.86), and that Al content is the factor that influences most SIA P solubility. Based on our findings, we recommend the use of the Al, Fe, and P oxalate extraction to predict the SIA P availability, instead of the widely used NAC method which extracts only P.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.156
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.229
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2021
Admission routes3
Has abstractyes

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