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Record W3212023738 · doi:10.1111/ggr.12409

Certification of Uranium Isotope Amount Ratios in a Suite of Uranium Ore Concentrate Certified Reference Materials

2021· article· en· W3212023738 on OpenAlexafffundabout
Ruoxi Zhang, Kenny Nadeau, Eduardo A. Gautier, Paola A. Babay, José Luis Ramella, Marian Vîrgolici, Andreea Elena Serban, V. Fugaru, Yoshiki Kimura, Célia Venchiarutti, Stephan Richter, Yetunde Aregbe, Zsolt Varga, Maria Wallenius, Klaus Mayer, Hana Seo, Jung Youn Choi, Csaba Tóbi, Mostafa Fayek, Ryan Sharpe, Kyle M. Samperton, Victoria D. Genetti, Rachel Lindvall, Jeremy Inglis, Joanna S. Denton, Andrew A. Reinhard, B.B.A. Francisco, Xiaolei Zhao, W.E. Kieser, Juan He, Ying Gao, Juris Meija, Ali El‐Jaby, Lu Yang, Zoltán Mester

Bibliographic record

VenueGeostandards and Geoanalytical Research · 2021
Typearticle
Languageen
FieldChemistry
TopicRadioactive element chemistry and processing
Canadian institutionsCanadian Nuclear Safety CommissionUniversity of OttawaUniversity of ManitobaNational Research Council Canada
FundersChina Scholarship CouncilNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of China
KeywordsUraniumCertified reference materialsIsotopes of uraniumIsotopeUranium oreReference valuesRadiochemistryNatural uraniumChemistryMineralogyEnvironmental scienceMaterials scienceMetallurgyPhysicsDetection limitChromatographyNuclear physics

Abstract

fetched live from OpenAlex

In this study, data from thirteen laboratories from around the world are presented for a successful certification of uranium isotope ratios in uranium ore concentrate (UOC) certified reference materials from the National Research Council Canada. Different mass spectrometric measurement principles (including SF‐ICP‐MS, quadruple ICP‐MS, TIMS, MC‐ICP‐MS, SIMS and AMS) and measurement procedures were employed. In general, data from all sources exhibit good consistency with TIMS and MC‐ICP‐MS showing superior performance. The three candidate UOC CRMs (UCLO‐1, UCHI‐1 and UPER‐1) have natural uranium isotope ratios with certified values of 0.5304(7) × 10 −4 , 0.5475(2) × 10 −4 and 0.5361(4) × 10 −4 for n ( 234 U)/ n ( 238 U) and 0.007 2563(13), 0.007 2563(10) and 0.007 2542(11) for n ( 235 U)/ n ( 238 U), respectively, with expanded uncertainty ( k = 2) applicable to the last digit of the value given in the parentheses. Information values for n ( 236 U)/ n ( 238 U) in these three CRMs, measured by AMS, are also provided: 10 × 10 −12 , 200 × 10 −12 and 22 × 10 −12 . The uncertainties of the proposed certified values of uranium isotope ratios in UOC CRMs are superior to available reference materials, and the values of n ( 234 U)/ n ( 238 U) and n ( 236 U)/ n ( 238 U) show significant variation among the three CRMs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.084
GPT teacher head0.375
Teacher spread0.292 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2021
Admission routes3
Has abstractyes

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