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Record W3216111651 · doi:10.1002/mas.21756

Collisional experiences with Dr. Pietro Traldi and the incredible group in Padova

2021· article· en· W3216111651 on OpenAlex
Raymond E. March

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMass Spectrometry Reviews · 2021
Typearticle
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsTrent University
Fundersnot available
KeywordsChemistryGroup (periodic table)Organic chemistry

Abstract

fetched live from OpenAlex

Two Early Classic period (ca. 250-600 CE) Maya carved, greenstone jade pendants, Specimens A and B, were recovered from the Pacbitun site in Belize in 1987. The specimens were visually similar and may have been cut from a common jade piece. Mass spectrometry was considered as a technique that could possibly be used to explore the similarity of the specimens. However, at that time, neither electrospray ionization nor matrix-assisted laser desorption/ionization (MALDI) had been discovered; furthermore, only elemental analysis had been carried out with jade samples and there were no accounts of polyatomic ions being produced from jade. The discoverer of the greenstone jade pendants, a faculty member in Anthropology at Trent University, sought the assistance of the author of this piece but no immediate progress was accomplished. About 7 years after discovery of the greenstone jade pendants, this author was invited to spend a short sabbatical leave in the laboratory of Dr. Pietro Traldi in Padova, Italy. While this invitation was attractive for several reasons, the principal attraction was Dr. Traldi's new, and mysterious acquisition of MALDI instrumentation. There was, perhaps, a single iota of reason that appeared to suggest unusual assistance of a matrix in liberating polyatomic ions from jade using laser irradiation. This account is of a very interesting sojourn with Dr. Traldi and members of his laboratory which did not lead to any immediate understanding of MALDI; however, the belief was constant for the next 20 years after which some progress was made in the exploration of the structure of jade.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.820
Threshold uncertainty score0.993

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0080.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.264
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it