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Record W4206476185 · doi:10.1039/d1sc05692a

Multi-resonant thermally activated delayed fluorescence emitters based on tetracoordinate boron-containing PAHs: colour tuning based on the nature of chelates

2022· article· en· W4206476185 on OpenAlexaff
Guoyun Meng, Lijie Liu, Zhechang He, David Hall, Xiang Wang, Tai Peng, Xiaodong Yin, Pangkuan Chen, David Beljonne, Yoann Olivier, Eli Zysman‐Colman, Nan Wang, Suning Wang

Bibliographic record

VenueChemical Science · 2022
Typearticle
Languageen
FieldEngineering
TopicOrganic Light-Emitting Diodes Research
Canadian institutionsQueen's University
FundersHenan Agricultural UniversityBeijing Institute of TechnologyNatural Science Foundation of Heilongjiang ProvinceTsinghua UniversityFonds De La Recherche Scientifique - FNRSNational Natural Science Foundation of ChinaWaalse GewestFédération Wallonie-BruxellesEngineering and Physical Sciences Research CouncilLeverhulme Trust
KeywordsTetracoordinateChelationFluorescenceBoronPhotochemistryMoleculeLigand (biochemistry)Quantum efficiencyChemistryCovalent bondIntersystem crossingOLEDAbsorption (acoustics)Materials scienceInorganic chemistryOrganic chemistryExcited stateOptoelectronics

Abstract

fetched live from OpenAlex

A new class of tetra-coordinate boron-containing MR-TADF emitters and their corresponding high-performance hyperfluorescent organic light-emitting diodes have been successfully achieved.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.453
Threshold uncertainty score0.714

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.241
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations55
Published2022
Admission routes1
Has abstractyes

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