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Record W4206737472 · doi:10.1002/cjce.24368

Precipitation of lithium phosphate from lithium solution by using sodium phosphate

2022· article· en· W4206737472 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2022
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsnot available
FundersKorea Institute of Geoscience and Mineral Resources
KeywordsLithium (medication)PrecipitationChemistryDistilled waterHydrolysisPhosphateSodiumNuclear chemistryInorganic chemistryChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Lithium was studied to precipitate into Li 3 PO 4 by adding Na 3 PO 4 under various experimental conditions such as initial lithium concentration of the solution, initial pH of the solution, temperature, and the mol equivalent ratio of Na 3 PO 4 . The precipitation mechanism of Li 3 PO 4 was investigated with the change of pH value of the solution over time. The precipitation efficiency of Li 3 PO 4 was 95.4% in the condition of the mol equivalent ratio of Na 3 PO 4 of 1, initial Li concentration of 7 g/L, initial pH of 9.5, and at 90°C. When Na 3 PO 4 was added three times, divided in the mol equivalent ratio of 1 via the hydrolysis reaction of PO 4 3− , which inhibits the Li 3 PO 4 precipitation reaction, an excellent precipitation efficiency of 98.4% was obtained. Co‐precipitated Na 2 HPO 4 with Li 3 PO 4 was washed by distilled water in the condition of solid/liquid ratio of 10% and at 90°C. The purity of the final Li 3 PO 4 product was found to be 99.1%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.152
Threshold uncertainty score0.456

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.207
Teacher spread0.196 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it