Recent Advances in the Luminescence of Arylboronic Acids and their Heteroatom Condensates
Bibliographic record
Abstract
Abstract Although organoboron compounds have long been used in optoelectronics, the majority of research has involved boron difluoride and borane type moieties. In recent years, there has been increased interest in the luminescence of boronic acids and their heteroatom condensates (BAHCs), a class which can demonstrate properties of fluorescence, mechanoluminescence, room temperature phosphorescence, aggregation induced emission (AIE), and thermally activated delayed fluorescence (TADF). This Review covers the literature until the end of 2020 on the inherent luminescence of tricoordinate arylboronates, grouped into azaborolines (Ar−BNY), boronic acids and esters (Ar−BO 2 ), with a particular focus on the impact of the boron atom on photophysical properties.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".