Probing the Thermodynamics of Moiré Patterns in Molecular Self-Assembly at the Liquid–Solid Interface
Bibliographic record
Abstract
Three types of moiré patterns, denoted as α-, β-, and γ-patterns, were observed in the molecular self-assembly of 1,3,5-tris(4-cyanophenyl)benzene (TCPB) on HOPG. Their relative stability was studied through thermally induced phase transitions monitored in situ by scanning tunneling microscopy. The incommensurate γ-pattern is thermodynamically more stable than the commensurate α- and β-patterns. The preference in the γ-pattern was explained by a static distortion wave, which was exclusively observed in this pattern. Through the lateral relaxation of TCPB lattice, the free energy of the γ-pattern can be reduced with respect to that of the α- and β-moiré patterns. This investigation provides insights into the thermodynamics of surface-confined supramolecular systems where the molecular lattice is incongruent with the substrate.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".