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Record W4214708436 · doi:10.1016/j.egyr.2022.02.124

Hydrothermally carbonized xylem sap for use in chemosensors, on and off switches, and memory devices

2022· article· en· W4214708436 on OpenAlexaff
Maria Semeniuk, Jimi Tjong, Zheng‐Hong Lu, Mohini Sain

Bibliographic record

VenueEnergy Reports · 2022
Typearticle
Languageen
FieldEngineering
TopicElectrochemical sensors and biosensors
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMaterials scienceCarbon fibersXylemNanotechnologyRaman spectroscopyTransistorField-effect transistorOptoelectronicsElectrical engineeringComposite material

Abstract

fetched live from OpenAlex

Multiple novel chemo sensor devices were created using hydrothermally synthesized fluorescent carbon produced from xylem sap. Most notably, UV light shone on the carbon can be used to selectively detect Fe3+ ions and pH by the “naked eye” instantly, a first for xylem-syrup-derived hydrocarbons. A large stroke shift is present with outstanding photo-stability, sensitivity. NOT, AND, and NOR logic gates were derived using this novel behaviour, and implemented in proof-of-concept applications including an on–off switch, a chemo sensor, and a memory device based on the fundamentals of transistors and hydrochar’s structural attributes. For the first time, characteristic crystalline sp2 carbon was observed in hydrochar xylem syrup, the results confirm 0.34 nm interlayer spacing and Raman spectroscopy displays an ID/IG ratio of 0.22 similar to graphitic structures. This material designed chemo sensor devices based on logic gates which have a significant broad potential to act as smart nano devices and displace traditional metal–oxide–semiconductor field-effect transistor (MOSFET) based circuits. The field of renewable hydrocarbon is the subject of a considerable, widening range of interest for a diverse field of applications that can be applied in innovative batteries, sensors, smart materials, healthcare and environmental monitoring.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.105
Threshold uncertainty score0.651

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.178
Teacher spread0.171 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2022
Admission routes1
Has abstractyes

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