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Record W4214834132 · doi:10.1111/maps.13800

Organic compounds in the Tarda C2 ungrouped carbonaceous chondrite: Evaluating the sources of contamination in a desert fall

2022· article· en· W4214834132 on OpenAlex
Libby D. Tunney, P. J. A. Hill, C. D. K. Herd, Robert W. Hilts

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueMeteoritics and Planetary Science · 2022
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAstro and Planetary Science
Canadian institutionsMacEwan UniversityUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Space Agency
KeywordsMeteoriteChondriteChemistryEnvironmental chemistryOrganic matterOrganic compoundContaminationMineralogyAstrobiologyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Studying organic compounds in meteorites provides important insight into the chemical processes that occurred in the early solar system. Once meteorites reach the Earth’s surface, they are subject to terrestrial organic contamination that may confound the conclusions that we draw from meteorite organic analyses. Within this study, specimens of the Tarda C2 ungrouped carbonaceous chondrite, collected within a few days of its fall on August 25, 2020, from a barren desert in Morocco, were analyzed for their organic compound contents. In addition, a sand sample from the strewn field was analyzed to confirm the sources of a handful of contaminating compounds detected in the Tarda stones. Using dichloromethane (DCM) rinses of the Tarda stone exteriors and DCM and hot water extractions of meteorite specimen powders and sand sample, and analysis of the soluble organics by gas chromatography‐mass spectrometry, we distinguish between extraterrestrial and contaminant sources for each organic compound. In this study, N ‐tert‐butyldimethylsilyl‐ N ‐methyltrifluoroacetamide (MTBSTFA) was used to derivatize the hot water extractions to utilize its single‐step derivatization reaction ability. The compounds determined to be intrinsic to Tarda include propanoic acid, propanedioic acid, butanedioic acid, fumaric acid, methylmaleic acid, threonine, proline, glycine, urea, and cyclic octaatomic sulfur. We detected numerous terrestrial organic compounds, all of which were traced back to the meteorites’ collection area, with several being confirmed in the sand sample. Our results have implications for best practices for the collection of freshly fallen meteorites, especially carbonaceous chondrites, as well as how specimens should be handled and curated after collection.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.146
Threshold uncertainty score0.600

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.248
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it