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Record W4214970126 · doi:10.1021/ct501032v.s001

Probing potential energy surface exploration strategies for complex\n systems

2014· preprint· en· W4214970126 on OpenAlexfundno aff
Gawonou Kokou N’Tsouaglo, Laurent Karim Béland, J.P. Joly, P.E. Brommer, Normand Mousseau, Pascal Pochet

Bibliographic record

VenuearXiv (Cornell University) · 2014
Typepreprint
Languageen
FieldEngineering
TopicIon-surface interactions and analysis
Canadian institutionsnot available
FundersIslamic Development BankFonds Québécois de la Recherche sur la Nature et les TechnologiesNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsStatistical physicsKinetic Monte CarloKinetic energyEnergy landscapeLattice (music)Complex systemRelaxation (psychology)Monte Carlo methodEnergy (signal processing)Tabu searchPotential energy surfacePhysicsComputer scienceAlgorithmMathematicsQuantum mechanicsThermodynamics

Abstract

fetched live from OpenAlex

The efficiency of minimum-energy\nconfiguration searching algorithms\nis closely linked to the energy landscape structure of complex systems,\nyet these algorithms often include a number of steps of which the\neffect is not always clear. Decoupling these steps and their impacts\ncan allow us to better understand both their role and the nature of\ncomplex energy landscape. Here, we consider a family of minimum-energy\nalgorithms based, directly or indirectly, on the well-known Bell–Evans–Polanyi\n(BEP) principle. Comparing trajectories generated with BEP-based algorithms\nto kinetically correct off-lattice kinetic Monte Carlo schemes allow\nus to confirm that the BEP principle does not hold for complex systems\nsince forward and reverse energy barriers are completely uncorrelated.\nAs would be expected, following the lowest available energy barrier\nleads to rapid trapping. This is why BEP-based methods require also\na direct handling of visited basins or barriers. Comparing the efficiency\nof these methods with a thermodynamical handling of low-energy barriers,\nwe show that most of the efficiency of the BEP-like methods lie first\nand foremost in the basin management rather than in the BEP-like step.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.809
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.067
GPT teacher head0.183
Teacher spread0.117 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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